Water and Irrigation Management

Water and Irrigation Management

Identification of Factors Affecting Nitrate Contamination in Ardabil Plain Aquifer Using Statistical Methods

Document Type : Research Paper

Authors
Mona Nemati 1
Mahmood Tabari 2
SEYED ABBAS Hosseini 1
saman Javadi 3
1 Department of Civil Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran.
2 Department of Civil Engineering, Faculty of Technology and Engineering, University of Mazandaran, Mazandaran, Iran.
3 Department of Irrigation and Drainage, College of Abouraihan, University of Tehran, Iran.
10.22059/jwim.2022.343545.995
Abstract
Nitrate is one of the pollutants that affects groundwater in most aquifers of the country. In order to investigate the behavior of hydrogeochemical parameters of groundwater in the Ardabil plain aquifer, the results of qualitative data of 139 wells that were measured in both wet and dry seasons during the water year 2012-2011 were used. Using XLSTAT software, contamination was identified and samples were classified using principal factor analysis (PCA) and hierarchical clustering (HCA). Factor analysis method led to the extraction of five factors affecting groundwater quality with a total variance of 68.09 percent. Also, the results of factor analysis showed that the first, fourth and fifth factors are due to geogenic processes and the second and third factors are due to anthropogenic processes. The results of the hierarchical clustering method divided the samples into three groups, each group having two subsets. The set related to cluster one is spread in the northern, eastern, southern and parts of the center, west by mix(agriculture-garden), medium pasture and dry farming as well as urban areas. The set of the second cluster is often spread in the central, western and urban areas of the aquifer, with mix(agriculture-garden) and residential areas. The set of third cluster has been expanded to southwestern and urban areas. Generally, the existence of dissolution and ion exchange processes on the one hand, as well as leaching of fertilizers and incomplete development of the sewage system in the aquifer on the other hand has provided the groundwater pollution.
Keywords
Anthropogenic
Principal factor analysis
Clustering
Geogenic
Nitrate
Subjects
  1. Adepelumi, A. A., Ako, B. D., Ajayi, T. R., Afolabi, O., & Omotoso, E. J. (2009). Delineation of saltwater intrusion into the freshwater aquifer of Lekki Peninsula, Lagos, Nigeria. Environmental Geology, 56(5), 927-933.
  2. Akbari, E., Nadiri, A. A., & Sadghi Aghdam, F. (2022). Hydrochemical Characteristics Investigation of Khoy Plain Aquifer and Determination of Probable Anomalies Sources. Water and Irrigation Management, 11(4), 867-883. (In Persian)
  3. Alami, M., Nourani, V., & Daneshvar Vousoughi, F. (2016). Using Spatial Clustering in Forecasting Groundwater Quality Parameters by ANFIS. Journal of Water and Wastewater; Ab va Fazilab (In persian), 27(3), 62-74.
  4. Ardabil Regional Water Authority. (2013). Investigation of Groundwater Balance in Ardabil Plain. Ardabil Regional
  5. Water Authority, Ardabil, Iran (In Persian).
  6. Boyd, C. E. (2019). Water quality: an introduction. Springer Nature.
  7. Dalton, M.G., & Upchurch, S.G. (1978). Interpretation of hydrochemical faces by factor analysis. Journal of Groundwater, 16(4), 228-233.
  8. Daneshvar vosoghi, F., & Dinpashoh, Y. (2013). Trend of groundwater quality of Ardabil plain using the spearman method. Journal of Environmental Studies, 38(64), 17-28. (In Persian)
  9. Dash, S., & Kalamdhad, A. S. (2021). Hydrochemical dynamics of water quality for irrigation use and introducing a new water quality index incorporating multivariate statistics. Environmental Earth Sciences, 80(3), 1-21.
  10. Darvishzadeh, A., (2018). Iran geological:Stratigraphy, Tectonic, Metamorphic and Magmatism. Tehran, AmirKabir;
  11. Driver, H. E., & Kroeber, A. L. (1932). Quantitative expression of cultural relationships(Vol. 31, No. 4). Berkeley: University of California Press.  Volume 31(4), 211-256.
  12. Ebrahimi Varzane, S., Zarei, H., TishehZan, P., & Akhondali, A. M. (2019). Evaluation of groundwater-surface water interaction by using cluster analysis (case study: western part of Dezful-Andimeshk plain). Iran-Water Resources Research, 15(3), 246-257 (In Persian).
  13. (2006). Hydrogeological assessment (groundwater quality) guideline. EPA Victoria, Publication 888, ISBN 0730676587, Australia.
  14. Everest, T., & Özcan, H. (2019). Applying multivariate statistics for identification of groundwater resources and qualities in NW Turkey. Environmental monitoring and assessment, 191(2), 1-17.
  15. Ferchichi, H., Ben Hamouda, M. F., Farhat, B., & Ben Mammou, A. (2018). Assessment of groundwater salinity using GIS and multivariate statistics in a coastal Mediterranean aquifer. International journal of environmental science and technology, 15(11), 2473-2492.
  16. Garg, V. K., Suthar, S., Singh, S., Sheoran, A., & Jain, S. (2009). Drinking water quality in villages of southwestern Haryana, India: assessing human health risks associated with hydrochemistry. Environmental Geology, 58(6), 1329-1340.
  17. Gharah mahmoudlou, M., & Raghimi, M., & Heshmat pour, A. (2007). Hydro geochemical study of Gorgan water sources using factor analysis and cluster analysis methods. Journal of environmental studies, 33(43), 73-82. (Persian)
  18. Ghahremanzadeh, H., Noori, R., Baghvand, A., & Nasrabadi, T. (2018). Evaluating the main sources of groundwater pollution in the southern Tehran aquifer using principal component factor analysis. Environmental geochemistry and health, 40(4), 1317-1328.
  19. Institute of Standards and Industrial Research of Iran (IDWS). (2010). Iranian drinking water standard -Physical and chemical specifications. ISIRI 1053, 5th.revision. (In Persian)
  20. Kannel, P. R., Lee, S., Kanel, S. R., & Khan, S. P. (2007). Chemometric application in classification and assessment of monitoring locations of an urban river system. Analytica Chimica Acta, 582(2), 390-399.
  21. khanduzi, F., Pari Zanganeh, A., Aamani, A., & Dadban Shahamat, Y. (2015). Survey of hydro-geochemical quality and health of groundwater in ramian, Golestan Province, Iran. Journal of Health Research in Community, 1(3), 41-52.
  22. Khodabakhshi, M., Karimzadeh, F., Khoshmanesh, B., & Zieazarifi, A. (2019). Investigating and identification of sources and parameters of water pollution in Karaj River in Islamshahr range. 12(45), 39-48
  23. Kord, M. (2014). Numerical Modeling of the Ardabil Plain Aquifer and Its Management Using Optimization of Groundwater Extraction. PhD thesis, Department of Geology, University of Tabriz, Tabriz, Iran. (In Persian).
  24. Kord, M., & Moghaddam, A. A. (2014). Spatial analysis of Ardabil plain aquifer potable groundwater using fuzzy logic. Journal of King Saud University-Science, 26(2), 129-140.
  25. Lawrence, F.W., & Upchurch, S. B. (1982). Identification of water recharges areas using geochemical factor analysis. Groundwater, 20, 680-687.
  26. Maghrebi, M., Noori, R., Bhattarai, R., Mundher Yaseen, Z., Tang, Q., Al‐Ansari, N., ... & Madani, K. (2020). Iran's Agriculture in the Anthropocene. Earth's Future, 8(9), e2020EF001547.
  27. Mahmoodi Nezhad, Y. (2012). The sources of nitrate in drinking wells of pasargad region. Master dissertation. Shiraz University. Iran. (In Persian)
  28. Nadiri, A. A., Moghaddam, A. A., Tsai, F. T., & Fijani, E. (2013). Hydrogeochemical analysis for Tasuj plain aquifer, Iran. Journal of earth system science, 122(4), 1091-1105.
  29. Nadiri, A., Ruzrakh, J., & Asgharimoghadam, A. (2016). Hydrogeochemical and hydrogeological study of Harzandat plain aquifer using multivariate statistical methods and graphical methods. Journal of Iran Water Research, 23(10), 111-122. (In Persian).
  30. Nag, S. K., & Das, S. (2014). Quality assessment of groundwater with special emphasis on irrigation and domestic suitability in Suri I & II blocks, Birbhum district, West Bengal, India. India Am J Water Resour, 2(4), 81-98.
  31. Nguyen, B. T., Nguyen, T. M. T., & Bach, Q. V. (2020). Assessment of groundwater quality based on principal component analysis and pollution source-based examination: a case study in Ho Chi Minh City, Vietnam. Environmental Monitoring and Assessment, 192(6), 1-13.
  32. Noori, R., Kerachian, R., Khodadadi Darban, A., & Shakibaienia, A. (2007). Assessment of importance of water quality monitoring stations using principal components analysis and factor analysis: A case study of the Karoon river. Journal of Water and Wastewater; Ab va Fazilab, 18(3), 60-69. (In persian).
  33. Noori, R., Farahni, F., Jun, C., Aradpour, S., Bateni, S. M., Ghazban, F., & Abolfathi, S. (2022). A non-threshold model to estimate carcinogenic risk of nitrate-nitrite in drinking water. Journal of Cleaner Production, 132432.
  34. Oudouris, K., Panagopoulos, A., & Koumantakis, J. (2000). Multivariate statistical analysis in the assessment of hydrochemistry of the Northern Korinthia prefecture alluvial aquifer system (Peloponnese, Greece). Natural Resources Research, 9(2), 135-146.
  35. Rahmanian, N., Ali, S. H. B., Homayoonfard, M., Ali, N. J., Rehan, M., Sadef, Y., & Nizami, A. S. (2015). Analysis of physiochemical parameters to evaluate the drinking water quality in the State of Perak, Malaysia. Journal of Chemistry.
  36. Rawat, R., & Siddiqui, A.R. (2019). Assessment of Physiochemical Characteristics of Drinking Water Quality in Allahabad Metropolitan City India. The Oriental Anthropol, 19(1), 121-135.
  37. Sanchez-Perez, J. M. & Tremolieres, M., (2003). Changes in groundwater chemistry as a consequence of suppressions of floods. Rhine floodplains case. Journal of Hydrolgy, 270, 89-04
  38. Shyu, G. S., Cheng, B. Y., Chiang, C. T., Yao, P. H., & Chang, T. K. (2011). Applying factor analysis combined with kriging and information entropy theory for mapping and evaluating the stability of groundwater quality variation in Taiwan. International journal of environmental research and public health, 8(4), 1084-1109.
  39. Srivastava, S.K., & Ramanathan, A.L. (2007). Geochemical assessment of groundwater quality in vicinity of Bhalswa landfill,
  40. Delhi, India, using graphical and multivariate statistical methods. Environmental Geology, 53, 1509-1528.
  41. Vasanthavigar, M., Srinivasamoorthy, K., Vijayaragavan, K., Rajiv Ganthi, R., Chidambaram, S., Anandhan, P., & Ward Jr, J. H. (1963). Hierarchical grouping to optimize an objective function. Journal of the American statistical association, 58(301), 236-244.
  42. World Health Organization (WHO). (2017) Guidelines for drinking-water quality. forth edition. incorporating the 1st ISBN 978 92 4 1549950.
  43. Yidana, S. M., & Yidana, A. (2010). An assessment of the origin and variation of groundwater salinity in southeastern Ghana. Environmental Earth Sciences, 61(6), 1259-1273.
Water and Irrigation Management
Volume 13, Issue 2
Summer 2023
Pages 527-550